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Derivation · draft

Grand-Canonical Ensemble and the Grand Potential

Statement

Builds the grand partition function Xi for systems exchanging particles with a reservoir and derives Phi = -k_B T ln Xi together with mean N and its fluctuations.

Depends on

Gibbs Entropy and the Maximum-Entropy Derivation of the Ensembles, Temperature, Pressure and Chemical Potential from Entropy Maximization

Used by

PU-302/L10