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Unit · year 3

PU-303 · Condensed Matter Physics

Threads matter · waves · energy · symmetry · chance · fields26 lectures18 derivations

The unit builds the quantum theory of solids from a single organizing principle—discrete translational symmetry—showing how periodicity forces electronic and vibrational states into Bloch waves and energy bands, and how band filling alone distinguishes metals, insulators, and semiconductors. It then confronts the failures of the independent-electron picture, developing the statistical and collective phenomena (Fermi statistics, lattice dynamics, superconductivity, magnetism) that make real condensed matter richer than the sum of its electrons.

PREREQUISITES

PU-104, PU-201, PU-202, PU-203, PU-205

Lectures

L01
What Condensed Matter Physics Asks
L02
Bravais Lattices, Bases, and Crystal Symmetry
L03
The Reciprocal Lattice and the Brillouin Zone
L04
X-ray Diffraction: Laue, Bragg, and the Structure Factor
L05
Reading Diffraction Patterns and Systematic Absences
L06
Electrons in a Periodic Potential: Bloch's Theorem
L07
The Nearly-Free-Electron Model and the Origin of Gaps
L08
The Tight-Binding Limit
L09
Metals, Insulators, and Semiconductors from Band Filling
L10
Semiclassical Dynamics and Effective Mass
L11
The Density of States and Van Hove Singularities
L12
The Free Electron Gas and Sommerfeld Theory
L13
Lattice Dynamics: The Diatomic Chain
L14
Phonons: Quantizing the Lattice
L15
Heat Capacity of Solids: Einstein and Debye
L16
Screening and the Failure of the Independent Electron
L17
Semiconductor Statistics and Doping
L18
Transport Theory and the Boltzmann Equation
L19
Electrons in Magnetic Fields: Landau Levels
L20
The Integer Quantum Hall Effect and Topology
L21
Magnetism I: Exchange and Mean-Field Order
L22
Magnetism II: Spin Waves and Magnons
L23
Superconductivity I: Phenomenology and the Cooper Problem
L24
Superconductivity II: The BCS Ground State and Gap
L25
Broken Symmetry, Order Parameters, and Collective Modes
L26
Synthesis: From One Symmetry to the Phases of Matter

Derivations homed in this unit

D-247

Reciprocal Lattice from the Bravais Lattice

Construct the reciprocal lattice as the set of wavevectors giving unit plane-wave phase on every Bravais lattice point, and derive its primitive vectors.

D-248

Laue and Bragg Diffraction Conditions

Show that constructive X-ray scattering from a crystal requires the momentum transfer to equal a reciprocal lattice vector, prove equivalence to Bragg's law, and obtain the structure factor governing systematic absences.

D-249

Bloch's Theorem from Translational Symmetry

Prove that eigenstates of a periodic Hamiltonian can be chosen as a plane wave times a lattice-periodic function, labelled by a crystal momentum in the first Brillouin zone.

D-250

Band Gaps in the Nearly-Free-Electron Model

Use degenerate perturbation theory at Brillouin-zone boundaries to show a weak periodic potential opens gaps of size twice the relevant Fourier component.

D-251

Tight-Binding Band Dispersion

Derive the band energy as a lattice Fourier sum of hopping integrals by expanding Bloch states in localized atomic orbitals.

D-252

Effective Mass and Semiclassical Electron Dynamics

Derive the semiclassical equations of motion for a Bloch electron and identify the inverse effective-mass tensor with the band curvature.

D-253

Density of States and Van Hove Singularities

Express the density of states as a Brillouin-zone surface integral over a band and show that band extrema and saddle points produce dimensionality-dependent singularities.

D-254

Sommerfeld Free-Electron Heat Capacity

Apply the Sommerfeld expansion to the Fermi-Dirac distribution to derive the linear-in-temperature electronic heat capacity of a degenerate electron gas.

D-255

Phonon Dispersion of the Diatomic Chain

Diagonalize the harmonic equations of motion for a diatomic linear chain to obtain acoustic and optical branches separated by a zone-boundary gap.

D-256

Quantization of Lattice Vibrations

Canonically quantize the normal modes of the crystal to obtain phonons as bosonic quasiparticles with creation and annihilation operators.

D-257

Debye Model and the T-cubed Heat Capacity

Integrate the phonon density of states with a linear dispersion and Debye cutoff to derive the low-temperature T-cubed lattice heat capacity and high-temperature Dulong-Petit limit.

D-258

Intrinsic Carrier Concentration in Semiconductors

Integrate the Fermi-Dirac occupation over parabolic conduction and valence bands to derive the law of mass action and the intrinsic carrier density's exponential temperature dependence.

D-259

Electrical Conductivity from the Boltzmann Equation

Solve the linearized Boltzmann equation in the relaxation-time approximation to derive the conductivity tensor and recover the Drude result from Fermi-surface averages.

D-260

Landau Levels and the Integer Quantum Hall Effect

Quantize a two-dimensional electron gas in a magnetic field into Landau levels and derive the quantized Hall conductance plateaus.

D-261

Cooper Pair Instability

Show that an arbitrarily weak attractive interaction binds a pair of electrons above a filled Fermi sea, signalling the instability of the normal metal.

D-262

BCS Gap Equation and the Superconducting Gap

Mean-field decouple the pairing Hamiltonian via a Bogoliubov transformation to derive the self-consistent gap equation and its critical temperature.

D-263

Weiss Mean-Field Theory of Ferromagnetism

Derive the self-consistent magnetization and Curie-Weiss susceptibility of the Heisenberg model in mean-field approximation, locating the ferromagnetic transition.

D-264

Spin-Wave Dispersion and Magnons

Apply the Holstein-Primakoff transformation to the Heisenberg ferromagnet to derive the quadratic magnon dispersion and the Bloch T-to-the-three-halves law.